KTP
Potassium Titanyl Phosphate (KTiOPO4 or KTP) is a nonlinear optical crystal, which possesses excellent nonlinear and electro-optic properties. It has large nonlinear optical coefficients and wide angular bandwidth and small walk-off angle, etc. which make it suitable for various nonlinear frequency conversion and wave guide online-ordering.
Due to very high effective nonlinearity (deff ~8.3×d36 (KDP) at 1.06μ m) and excellent optical properties, KTP perfectly suits as lasing material in various online-ordering. The phase matching range of KTP crystal lies in 0.99-3.3 μ m region .This allows us to use KTP as an intracavity and extracavity frequency double for the most commonly used lasers, such as Nd:YAG, Nd:Glass and Nd:YLF.
Properties
Crystal Structure |
Orthorhombic, space group Pna21,point group mm2 |
Lattice Parameter |
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Melting Point |
About 1172°C |
Mohs Hardness |
5 |
Density |
3.01g/cm3 |
Thermal Conductivity |
13W/m·K |
Thermal Expansion Coefficient |
αx=11x10-6/°C, αy=9x10-6/°C,αz=0.6x10-6/°C |
Transparency Range |
350~4500nm |
SHG PM Range |
497~1800nm(Type II) |
Thermal-optical Coefficients(/°C) |
dnx/dT=1.1X10-5
dny/dT=1.3X10-5
dnz/dT=1.6X10-5 |
Absorption Coefficients |
<0.1%/cm at 1064nm; <1%/cm at 532nm |
For Type II SHG of a Nd:YAG laser at 1064nm |
Temperature Acceptance: 24°C-cm
Spectral Acceptance: 0.56nm-cm
Angular Acceptance: 14.2mrad-cm(φ); 55.3mrad-cm (θ)
Walk-off Angle: 0.55° |
NLO Coefficients |
deff(II)≈(d24-d15)sin2φsin2θ-(d15sin2φ+d24cos2φ)sinθ |
Non-vanished NLO susceptibilities |
d31=6.5pm/V ;d24=7.6pm/V; d32=5pm/V ;d15=6.1 pm/V; d33=13.7pm/V |
Sellmeier Equations
(λ in μm) |
nx2=3.0065+0.03901/(λ2-0.04251)-0.01327λ2
ny2=3.0333+0.04154/(λ2-0.04547)-0.01408λ2
nz2=3.3134+0.05694/(λ2-0.05658)-0.01682λ2 |
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KTPs Applications
- Frequency doubling (SHG) of Nd-doped lasers for green/red outputs.
- Frequency mixing (SFM) of Nd lasers and diode lasers for blue outputs.
- Parametric sources (OPG, OPA and OPO) for 600nm-4500nm tunable outputs.
- E-O modulators, optical switches, directional couplers.
- Optical waveguides for integrated NLO and E-O devices
Specification of Sino-crystal's KTP
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